抄録
The asymmetric Payne oxidation of N-sulfonyl imines catalyzed by a P-spiro chiral triaminoiminophosphorane was developed for the practical synthesis of optically active N-sulfonyl oxaziridines. High efficiency and an excellent level of enantioselectivity were generally achieved with a wide variety of aldimines by choosing appropriate reaction conditions. The versatility of this method was demonstrated by the diastereoselective kinetic oxidation of racemic α-chiral N-sulfonyl imines.
| 本文言語 | English |
|---|---|
| 論文番号 | 5440 |
| ページ（範囲） | 871-878 |
| ページ数 | 8 |
| ジャーナル | Synthesis (Germany) |
| 巻 | 46 |
| 号 | 7 |
| DOI | |
| 出版ステータス | Published - 2014 4月 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 触媒
- 有機化学