The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins

Fumitoshi Kakiuchi; Taisuke Sato; Kimitaka Igi; Naoto Chatani; Shinji Murai

doi:10.1246/cl.2001.386

The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins

Fumitoshi Kakiuchi
, Taisuke Sato
, Kimitaka Igi
, Naoto Chatani
, Shinji Murai

研究成果: Article › 査読

95 被引用数 (Scopus)

抄録

The addition of a β C-H bond to the formyl group of aldehydes to olefins took place with the aid of Ru(H)₂(CO)(PPh₃)₃ as a catalyst. Several olefins can be used in the catalytic reaction of conjugate enals. The presence of a sterically hindered substituent at the ortho position of benzaldehyde and the presence of an electron donating substituent appear to be important factor in accomplishing the desired coupling reaction.

本文言語	English
ページ（範囲）	386-387
ページ数	2
ジャーナル	Chemistry Letters
号	5
DOI	https://doi.org/10.1246/cl.2001.386
出版ステータス	Published - 2001
外部発表	はい

ASJC Scopus subject areas

化学一般

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10.1246/cl.2001.386

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AU - Murai, Shinji

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The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins

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