@article{81216214b020437b8b11020fd18cda83,
title = "The stereoselective construction of all-carbon quaternary stereocenters by allylations and its application to synthetic studies of natural products",
abstract = "The synthesis of organic compounds containing all.. carbon quaternary stereocenters through the addition of allylmetals to aldehydes is still a challenge. In this account we describe two methods to achieve this transformation stereoselectively: One involves the zinc-mediated Barbier-type allylation and the other allylboration of a sugar.. derived aldehyde. These methods were applied to the total synthesis of (+)-vibsanin A, and the synthesis of the tricyclic core of (-)-callophycoic acid A.",
author = "Akihiro Sakama and Akihiro Ogura and Keisuke Yoshida and Takao, {Ken Ichi}",
note = "Funding Information: We thank Professor Kin─ichi Tadano (Itsuu Laboratory) for helpful discussions and comments. We gratefully acknowledge our co─workers who participated in these research projects, and their names appear in the reference section. This work was supported in part by the MEXT─Supported Program for the Strategic Research Foundation at Private Universities, 2012─2016, and the Keio University Doctorate Student Grant─ in─Aid Program. Publisher Copyright: {\textcopyright} 2020 Society of Synthetic Organic Chemistry. All rights reserved.",
year = "2020",
month = nov,
day = "1",
doi = "10.5059/yukigoseikyokaishi.78.1039",
language = "English",
volume = "78",
pages = "1039--1047",
journal = "Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry",
issn = "0037-9980",
publisher = "Society of Synthetic Organic Chemistry",
number = "11",
}