The synthesis of hexafluorosumanene and its congeners

Bernd M. Schmidt; Berit Topolinski; Shuhei Higashibayashi; Tatsuhiro Kojima; Masaki Kawano; Dieter Lentz; Hidehiro Sakurai

doi:10.1002/chem.201204622

The synthesis of hexafluorosumanene and its congeners

Bernd M. Schmidt, Berit Topolinski, Shuhei Higashibayashi, Tatsuhiro Kojima, Masaki Kawano, Dieter Lentz, Hidehiro Sakurai

研究成果: Article › 査読

35 被引用数 (Scopus)

抄録

Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential.

本文言語	English
ページ（範囲）	3282-3286
ページ数	5
ジャーナル	Chemistry - A European Journal
巻	19
号	10
DOI	https://doi.org/10.1002/chem.201204622
出版ステータス	Published - 2013 3月 4
外部発表	はい

ASJC Scopus subject areas

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有機化学

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10.1002/chem.201204622

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AU - Lentz, Dieter

AU - Sakurai, Hidehiro

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The synthesis of hexafluorosumanene and its congeners

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