Thermal decarboxylative Nazarov cyclization of cyclic enol carbonates involving chirality transfer

Akane Kozuma; Keiichi Komatsuki; Kodai Saito; Tohru Yamada

doi:10.1246/cl.190763

Thermal decarboxylative Nazarov cyclization of cyclic enol carbonates involving chirality transfer

Akane Kozuma, Keiichi Komatsuki, Kodai Saito, Tohru Yamada

化学科

研究成果: Article › 査読

11 被引用数 (Scopus)

抄録

Decarboxylative Nazarov cyclization of chiral cyclic enol carbonates proceeded to afford chiral 2-cyclopentenones with excellent chirality transfer under thermal conditions without any catalyst. Interestingly, the thermal decarboxylative Nazarov cyclization furnished the desired product with better chirality transfer than the Lewis acid-catalyzed reaction.

本文言語	English
ページ（範囲）	60-63
ページ数	4
ジャーナル	Chemistry Letters
巻	49
号	1
DOI	https://doi.org/10.1246/cl.190763
出版ステータス	Published - 2020

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.190763

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title = "Thermal decarboxylative Nazarov cyclization of cyclic enol carbonates involving chirality transfer",

abstract = "Decarboxylative Nazarov cyclization of chiral cyclic enol carbonates proceeded to afford chiral 2-cyclopentenones with excellent chirality transfer under thermal conditions without any catalyst. Interestingly, the thermal decarboxylative Nazarov cyclization furnished the desired product with better chirality transfer than the Lewis acid-catalyzed reaction.",

keywords = "Chirality transfer, Decarboxylation, Electrocyclization",

author = "Akane Kozuma and Keiichi Komatsuki and Kodai Saito and Tohru Yamada",

note = "Publisher Copyright: {\textcopyright} 2020 The Chemical Society of Japan.",

year = "2020",

doi = "10.1246/cl.190763",

language = "English",

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pages = "60--63",

journal = "Chemistry Letters",

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T1 - Thermal decarboxylative Nazarov cyclization of cyclic enol carbonates involving chirality transfer

AU - Kozuma, Akane

AU - Komatsuki, Keiichi

AU - Saito, Kodai

AU - Yamada, Tohru

PY - 2020

Y1 - 2020

N2 - Decarboxylative Nazarov cyclization of chiral cyclic enol carbonates proceeded to afford chiral 2-cyclopentenones with excellent chirality transfer under thermal conditions without any catalyst. Interestingly, the thermal decarboxylative Nazarov cyclization furnished the desired product with better chirality transfer than the Lewis acid-catalyzed reaction.

AB - Decarboxylative Nazarov cyclization of chiral cyclic enol carbonates proceeded to afford chiral 2-cyclopentenones with excellent chirality transfer under thermal conditions without any catalyst. Interestingly, the thermal decarboxylative Nazarov cyclization furnished the desired product with better chirality transfer than the Lewis acid-catalyzed reaction.

KW - Chirality transfer

KW - Decarboxylation

KW - Electrocyclization

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U2 - 10.1246/cl.190763

DO - 10.1246/cl.190763

M3 - Article

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JO - Chemistry Letters

JF - Chemistry Letters

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Thermal decarboxylative Nazarov cyclization of cyclic enol carbonates involving chirality transfer

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