Thermosensitive gold nanoclusters stabilized by well-defined vinyl ether star polymers: Reusable and durable catalysts for aerobic alcohol oxidation

Shokyoku Kanaoka, Naoto Yagi, Yukiko Fukuyama, Sadahito Aoshima, Hironori Tsunoyama, Tatsuya Tsukuda, Hidehiro Sakurai

研究成果: Article査読

204 被引用数 (Scopus)

抄録

Au nanoclusters of less than 4 nm with a narrow size distribution were prepared and supported in thermosensitive vinyl ether star polymers obtained by living cationic polymerization. The thermosensitivity of the star polymers permitted easy separation of the clusters from the reaction mixture without any negative aggregation. Thus, the Au clusters could be recovered for reuse several times to induce alcohol oxidation with similar reactivity in each run.

本文言語English
ページ(範囲)12060-12061
ページ数2
ジャーナルJournal of the American Chemical Society
129
40
DOI
出版ステータスPublished - 2007 10月 10
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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