Total synthesis of (-)-anisatin

Akihiro Ogura; Kohei Yamada; Satoshi Yokoshima; Tohru Fukuyama

doi:10.1021/ol300390k

Total synthesis of (-)-anisatin

Akihiro Ogura, Kohei Yamada, Satoshi Yokoshima, Tohru Fukuyama

研究成果: Article › 査読

40 被引用数 (Scopus)

抄録

A novel synthetic route to (-)-anisatin has been developed. Our synthesis features a rhodium-catalyzed 1,4-addition of an arylboronic acid, an intramolecular Diels-Alder reaction of an ortho-quinone monoketal, a stereoselective [2,3]-Wittig rearrangement, and construction of the oxabicyclo [3.3.1] skeleton via cleavage of an epoxide by a primary amide.

本文言語	English
ページ（範囲）	1632-1635
ページ数	4
ジャーナル	Organic Letters
巻	14
号	6
DOI	https://doi.org/10.1021/ol300390k
出版ステータス	Published - 2012 3月 16
外部発表	はい

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol300390k

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Total synthesis of (-)-anisatin

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