Total synthesis of broussonetine F: The orthoamide overman rearrangement of an allylic diol

Naoto Hama; Toshihiro Aoki; Shohei Miwa; Miki Yamazaki; Takaaki Sato; Noritaka Chida

doi:10.1021/ol102856j

Total synthesis of broussonetine F: The orthoamide overman rearrangement of an allylic diol

Naoto Hama, Toshihiro Aoki, Shohei Miwa, Miki Yamazaki, Takaaki Sato, Noritaka Chida

応用化学科

研究成果: Article › 査読

41 被引用数 (Scopus)

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A first total synthesis of broussonetine F from diethyl l-tartrate was achieved. The cornerstone of our synthesis was an orthoamide Overman rearrangement, which provided an allylic amino alcohol with complete diastereoselectivity.

本文言語	English
ページ（範囲）	616-619
ページ数	4
ジャーナル	Organic Letters
巻	13
号	4
DOI	https://doi.org/10.1021/ol102856j
出版ステータス	Published - 2011 2月 18

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol102856j

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abstract = "A first total synthesis of broussonetine F from diethyl l-tartrate was achieved. The cornerstone of our synthesis was an orthoamide Overman rearrangement, which provided an allylic amino alcohol with complete diastereoselectivity.",

author = "Naoto Hama and Toshihiro Aoki and Shohei Miwa and Miki Yamazaki and Takaaki Sato and Noritaka Chida",

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AU - Hama, Naoto

AU - Aoki, Toshihiro

AU - Miwa, Shohei

AU - Yamazaki, Miki

AU - Sato, Takaaki

AU - Chida, Noritaka

PY - 2011/2/18

Y1 - 2011/2/18

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Total synthesis of broussonetine F: The orthoamide overman rearrangement of an allylic diol

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