Total synthesis of (+)-clavilactone A and (-)-clavilactone B by ring-opening/ring-closing metathesis

Ken Ichi Takao; Ryuki Nanamiya; Yuuki Fukushima; Ayumi Namba; Keisuke Yoshida; Kin Ichi Tadano

doi:10.1021/ol4027842

Total synthesis of (+)-clavilactone A and (-)-clavilactone B by ring-opening/ring-closing metathesis

Ken Ichi Takao, Ryuki Nanamiya, Yuuki Fukushima, Ayumi Namba, Keisuke Yoshida, Kin Ichi Tadano

応用化学科

研究成果: Article › 査読

45 被引用数 (Scopus)

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The enantioselective total synthesis of natural enantiomers of clavilactones A and B has been achieved. A key feature of the synthesis is the use of a ring-opening/ring-closing metathesis, which allows the one-pot transformation of a strained cyclobutenecarboxylate into a γ-butenolide.

本文言語	English
ページ（範囲）	5582-5585
ページ数	4
ジャーナル	Organic Letters
巻	15
号	21
DOI	https://doi.org/10.1021/ol4027842
出版ステータス	Published - 2013 11月 1

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol4027842

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AU - Namba, Ayumi

AU - Yoshida, Keisuke

AU - Tadano, Kin Ichi

PY - 2013/11/1

Y1 - 2013/11/1

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AB - The enantioselective total synthesis of natural enantiomers of clavilactones A and B has been achieved. A key feature of the synthesis is the use of a ring-opening/ring-closing metathesis, which allows the one-pot transformation of a strained cyclobutenecarboxylate into a γ-butenolide.

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Total synthesis of (+)-clavilactone A and (-)-clavilactone B by ring-opening/ring-closing metathesis

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