@article{93a1c37215c74de59465964e5abd72d9,
title = "Total Synthesis of Natural Products Using Intramolecular Nozaki-Hiyama-Takai-Kishi Reactions",
abstract = "In this Account, we describe our studies on the total synthesis of several natural products using intramolecular Nozaki-Hiyama-Takai-Kishi (NHTK) reactions. In each synthesis, an NHTK reaction is used to efficiently construct a medium-sized ring. These examples demonstrate the utility of the intramolecular NHTK reaction in natural product synthesis. 1 Introduction 2 Total Synthesis of (+)-Pestalotiopsin A 3 Total Synthesis of (+)-Cytosporolide A 4 Total Synthesis of (+)-Vibsanin A 5 Total Syntheses of (+)-Aquatolide and Related Humulanolides 6 Conclusion.",
keywords = "all-carbon quaternary stereocenters, cyclization, cycloaddition, medium-sized rings, metathesis, total synthesis",
author = "Takao, {Ken Ichi} and Akihiro Ogura and Keisuke Yoshida and Siro Simizu",
note = "Funding Information: This work was supported by the MEXT-Supported Program for the Strategic Research Foundation at Private Universities, 2012–2016, Japan Society for the Promotion of Science (JSPS), Grants-in-Aid for Scientific Research (KAKENHI) (Grant Nos. 15750094 and 15K05504) from Japan Society for the Promotion of Science (JSPS), the Naito Foundation, and the Keio Gijuku Academic Development Funds.JapanSocietyforthePromotionofScience(15750094)JapanSocietyforthePromotionofScience(15K05504)NaitoFoundation()KeioUniversity() Publisher Copyright: {\textcopyright} 2020 Georg Thieme Verlag. All rights reserved.",
year = "2020",
month = mar,
day = "17",
doi = "10.1055/s-0039-1691580",
language = "English",
volume = "31",
pages = "421--433",
journal = "Synlett",
issn = "0936-5214",
publisher = "Georg Thieme Verlag",
number = "5",
}