@article{be830c534d83495aa8f7a2da5ebaa9f8,
title = "Two-dimensional octacyano-bridged Mn(II)-Nb(IV) bimetal assembly with four different configurations of 3-hydroxypyridines",
abstract = "We report the crystal structure and magnetic properties of a two-dimensional cyano-bridged MnII(S = 5/2)-NbIV(S = 1/2) bimetal assembly (1), and the magnetic properties of an isostructural cyano-bridged MnII-MoIV(S = 0) bimetal assembly (2). 1 contains 3-hydroxypyridine ligands with four types of coordination arrangements, includes μ-oxo-bridged Mn-Mn sites, and shows ferrimagnetism with a Curie temperature of 16 K due to the antiferromagnetic MnII-NbIV superexchange interaction through the cyano groups. 2 exhibits paramagnetism with the antiferromagnetic interaction between Mn and Mn through the μ-oxo-bridges.",
keywords = "Antiferromagnetic superexchange interaction, Cyano-bridged bimetal assembly, Ferrimagnetism, Manganese, Niobium, Octacyanoniobate",
author = "Daisuke Takahashi and Koji Nakabayashi and Shu Tanaka and Ohkoshi, {Shin Ichi}",
note = "Funding Information: The present research was supported partly by the CREST program of JST , a Grant-in-Aid for Young Scientists (S) from JSPS , the Global COE Program “Chemistry Innovation through Cooperation of Science and Engineering”, Advanced Phonon Science Alliance (APSA) from MEXT Japan , the Asahi Glass Foundation , the Center for Nano Lithography & Analysis , The University of Tokyo , supported by MEXT Japan, and the Photon Factory Program Advisory Committee ( 2009G678 ). S. T. is partially supported by Grand-in-Aid for JSPS Fellows (23–7601). ",
year = "2013",
month = jan,
doi = "10.1016/j.inoche.2012.09.021",
language = "English",
volume = "27",
pages = "47--50",
journal = "Inorganic Chemistry Communications",
issn = "1387-7003",
publisher = "Elsevier BV",
}