Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform

Yujiro Hayashi; Mitsuhiro Takeda; Mitsuru Shoji; Masataka Morita

doi:10.1246/cl.2007.68

Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform

Yujiro Hayashi, Mitsuhiro Takeda, Mitsuru Shoji, Masataka Morita

研究成果: Article › 査読

抄録

Dramatic acceleration of the Diels-Alder reaction of acrylate ester or methacrolein with cyclopentadiene has been observed under ultracentrifugation conditions in the presence of water, when water-CHCl₃ two-phase system was employed. The Diels-Alder reaction proceeds in the lower organic phase under ultracentrifugation-induced high pressure with the upper water phase acting like a weight.

本文言語	English
ページ（範囲）	68-69
ページ数	2
ジャーナル	Chemistry Letters
巻	36
号	1
DOI	https://doi.org/10.1246/cl.2007.68
出版ステータス	Published - 2007 1月 5
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.2007.68

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title = "Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform",

abstract = "Dramatic acceleration of the Diels-Alder reaction of acrylate ester or methacrolein with cyclopentadiene has been observed under ultracentrifugation conditions in the presence of water, when water-CHCl3 two-phase system was employed. The Diels-Alder reaction proceeds in the lower organic phase under ultracentrifugation-induced high pressure with the upper water phase acting like a weight.",

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AB - Dramatic acceleration of the Diels-Alder reaction of acrylate ester or methacrolein with cyclopentadiene has been observed under ultracentrifugation conditions in the presence of water, when water-CHCl3 two-phase system was employed. The Diels-Alder reaction proceeds in the lower organic phase under ultracentrifugation-induced high pressure with the upper water phase acting like a weight.

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Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform

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